That's what I did with the used tank I got for my pond fish to winter in. I just used a razor scraper to cut the silicone out of the corners, then applied a new bead. Just be careful not to cut into the joint itself. The joints on my tank were good, so I saw no need to cut them apart. I'd probably end up breaking the glass doing that anyway. If it looks like the silicone in the joint is failing, then that would be another matter.
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I retired and got a fixed income but it's broke.
Ed
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50 gallon FOWLR, 10 gallon sump.
130 gallon reef, 20 gallon sump, 10 gallon refugium.
10 gallon quarantine.
60 gallon winter tank for pond fish.
300 gallon pond with waterfall.
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