you could possibly try changing the landscape up in the tank and see if that helps. Odds are if the female has made up her mind and is picking on him its not going to end well for the fish. Did this just start out of no where? any signs that could lead to this happening? feeding enough? any anemone to host? etc
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65 gallon saltwater tank, 60lbs live sand, 85lbs live rock, 2 ocellaris clowns, spotted goby, Flame hawkfish, scopas tang, numerous corals 
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