If it helps, I recently added a neon dottyback to my 75 gallon and it seems to get along with the other fish. It chased the six line wrasse a little for the first day or two but now they seem to co exist without problem. In fact, the small kole tang likes to follow the dottyback around the tank and through the rocks and the dottyback doesn't seem to mind.
However, I think that if you want some of those other small fish like firefish etc. it might be best to add them first and let them get established and add the dottyback last.
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