Hey Justin, I've never kept them before, but I found this on the web for you.
Hope it helps:
Social Behaviors:
In their natural environment Neon Gobies are seen singly, in pairs, and also in groups of 30 or more. A good community fish, the Neon Gobies are generally not aggressive except to members of their own species, unless they are a mated pair.
They will set up and defend territories if there is more than one.
They will also set up "cleaning stations". Other fish will indicate their desire to be cleaned by tilting and spreading their fins, and sometimes by changing color.
They can be kept with a variety of small and medium sized fish as well as corals and invertebrates. Be cautious with some larger fish and predatory type fish.
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