Reefer_rob,
I bake the baking soda for about 1 hr at 350F. I do this in mass quantities and then store it in zip lock bags. I bake it to drive off carbon dioxide which otherwise will lower your pH, not because it will dissolve easier in water.
Baking soda is such a hassle and I to have problems with over saturation...not the easiest stuff to dissolve ugh!
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