You know I am a big proponent of overskimming (I actually don't think you can) so if I was you I would go ahead and throw it on your 75g. It will probably do nothing but good for it.
My new skimmer is a Bubble King 500 ext. I bought it for the 300g cube I will be setting up (sigh - someday) but for now I am going to run it on my 190g. It is rated for a lot bigger system than this (can't recall off the top of my head).
Anyway you have bought yourself a very nice skimmer and I know that would not have the patience to wait until I got a new system set up - it would be fired up ASAP.
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